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劉陵崗研究員
 

 

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　劉陵崗－構造化學
 
  • 中央研究院化學研究所研究員
  • 台灣大學化學系教授
  • 民國61年台灣大學化學系學士
  • 民國67年德州大學奧斯丁校區化學系博士
  • 民國67-68年博士後研究馬蒲煤研究所
  • 民國68-74年副研究員中央研究院化學研究所
  • 民國70-74年副教授台灣大學化學系
  • 民國75-76年訪問學者加州大學柏克萊校區學系
  • 民國81-82年訪問教授馬里蘭大學化學系
  • 中國化學會、美國化學會、美國結晶學會會員

Tel：
886-2-27898532
Fax：
 886-2-27831237
mail：
 liuu chem.sinica.edu.tw


 
 
 
 
   
 

研究領域：

  • 功能性離子液體：定床化均相觸媒之回收和再利用；旋光性離子液體觸媒之不對稱反應研究；環氧烷類在超臨界二氧化碳流體中的觸媒環化加成反應；咪唑化合物及碳烯化合物兩物種間相互轉換的化學研究。
  • 連鎖式電子轉移觸媒反應：利用自由基反應路徑，提升無機化學與金屬有機化學中特定反應的速率和選擇性；合成新穎的化合物結構，研究新穎結構的性質。
  • 矽倍半氧衍生物的結構化學：修飾與官能基化立方體矽倍半氧化合物之表面，進行限制性的反應研究；製備奈米含芳香系發光官能基團之染料及其應用。

代表作：

  1. Adeyemi, O. G.; Liu, L.-K. Neighboring Metal Induced Oxidative Addition at the Iron Center Amongst the Iron-Arylpyridylphosphine Complexes. Inorg. Chim. Acta 2009, 362, 477.

  2. Chuang, P.-N.; Wu, T.-D.; Liu, L.-K. Increased Conversion to 2,4,6-triarylpyrylium Salt. Aldol Cyclotri- Merization of Acetophenone in BMImPF6 Ionic Liquid. J. Chin. Chem. Soc. (Taipei) 2008, 55, 512.

  3. Lu, N.; Chen, S.-C.; Lin, Y.-C.; Cheng, Y.-Y.; Liu, L.-K. High Fluorine Content Bis(fluoro-ponytailed) biPyridine Palladium Complexes as Catalyst for Mizoroki-Heck Reactions Under Fluorous Biphasic catalysis Conditions. J. Chin. Chem. Soc. (Taipei) 2008, 55, 89.

  4. Lu, N.; Chen, S.-C.; Chen, T.-C.; Liu, L.-K. Palladium-Catalyzed Heck Reaction Under Thermomorphic
    Mode. Tetrahed. Lett. 2008, 49, 371.

  5. Lu, N.; Lin, Y.-C.; Chen, J.-Y.; Fan, C.-W.; Liu, L.-K. New bis(fluoro-ponytailed) bipyridine ligands for Pd-catalyzed Heck reactions under fluorous biphasic catalysis condition. Tetrahedron 2007, 63, 2019.

  6. Adeyemi, O. G.; Liu, L.-K. Electron-transfer chain catalysis in phosphine replacement reaction: Determination of relative donor capability of arylpyridylphosphines. Inorg. Chim. Acta.2007, 360, 2464.

  7. Lu, N.; Lin, Y.-C.; Chen, J.-Y.; Chen, T.-C.; Chen, S.-C.; Wen, Y.-S.; Liu, L.-K. Synthesis, structure and reactivity of novel palladium-dichloride-2,2'-bipyridine with 4,4'-bis(fluorous-ponytail). Polyhedron 2007, 26, 3045.

  8. Lu, N.; Chen, J. Y.; Fan, C. W.; Lin, Y. C.; Wen, Y. S.; Liu, L.-K. (2,2'-bipyridine)palladiumdichloride derivatives as recyclable catalysts in Heck reactions. J. Chin. Chem. Soc. (Taipei, Taiwan) 2006, 53, 1517.

  9. Dare, E. O.; Liu, L.-K.; Peng, J. Modified procedure for improved synthesis of some octameric silsesquioxanes via hydrolytic polycondenzation in the presence of Amberlite ion-exchange resins. Dalton Trans. 2006, 3668.

  10. Dare, E. O.; Liu, L.-K. Organosilicon chemistry I: Cyclopropanation by carbene or carbenoid addition to an allylic silane. Bull. Chem. Soc. Ethiop. 2006, 20, 55.

  11. Li, X. L.; Liu, L.-K.; Hou, N.; Liu, G. Q.; Liu, C. G. SSR and SCAR markers linked to the fertility-restoring gene for a D-2-type cytoplasmic male-sterile line in wheat. Plant Breeding 2005, 124, 413.

  12. Liu, L.-K. Preparation and Reactions of Octasilsesquioxanes. Chin. J. Synth. Chem. 2004, 12, 118.
  13. Chang, W.-F.; Wen, Y.-S.; Liu, L.-K. 3,6-Bis(2-pyridyl)-di-1,2,4-triazolo[3,4-a:4',3'-c]phthalazine. Acta Cryst. 2004, C60, o665.

  14. Liu, L.-K.; Dare, E. O. Octasilsesquioxane chemistry II. Hydrosilylation reaction of octa(hydrido)silsesquioxane with unsaturated substrates and product properties. J. Chin. Chem. Soc. 2004, 51, 175.

  15. Liu, L.-K.; Hu, L.; Dong, Z. J. A glucosylceramide with a novel ceramide and three novel ceramides from the basidiomycete Cortinarius umidicola. Lipids 2003, 38, 669.

  16. Su, C. C.; Lu, L. H.; Liu, L.-K. Comparative study of molecular mechanics and theoretical conformational analysis of a new 16-crown-5 ether via X-ray crystallography and NMR spectroscopy. J. Phys. Chem. A 2003, 107, 4563.

  17. Liu, L.-K.; Chu, J.-B.; Slanina, Z.; Chow, T. J. Octasilsesquioxane chemistry I. Attachment of four surface bridges to octasilsesquioxane quasi-cube framework. J. Chin. Chem. Soc. 2002, 49, 943.

  18. Peng, J.; Liu, L.-K. Application of electron-transfer chain catalysis: Preparation of bridged [{(h5-C5H5)Fe(CO)2}2(m-diphosphine)2+] complexes without chelated [(h5-C5H5)Fe(CO)(h2-diphosphine)+] byproducts. C. R. Chimie 2002, 5, 319.

  19. Liu, L.-K.; Peng, J.; Huang, C. Preparation and Structure of [(h5-C5H5)Fe(CO){C(O)Ph}2]2Li2(2,2'-bipyridine): A Sequential Treatment of Nucleophile Followed by Lewis Base. J. Chin. Chem. Soc. 2002, 49, 311.

  20. Adeyemi, O. G.; Liu, L.-K. Abstraction of endo-H of (h4-BuC5H5)Fe(CO)2PPh3-nPyn (n = 1 and 2) Using Lewis Acids. Synth. React. Inorg. Met.-Org. Chem. 2001, 31, 737.

  21. Adeyemi, O. G.; Liu, L.-K. The Phosphine-exchange Reaction with an Equimolar Mixture of [(h5-C5H5)Fe(CO)2PPh3]+[PF6]- and P(2-C4H3O)3 (C4H3O = Furanyl). Bull. Chem. Soc. Ethiop. 2001, 15, 23.

  22. Peng, J.; Wen, Y.-S.; Liu, L.-K. Reaction of (h5-C5H5)Fe(CO)2I with Anionic Bidentate Phosphine Ligands PPh2(o-C6H4NHLi) or PPh2(o-C6H4OLi). J. Chin. Chem. Soc. 2001, 48, 833.

  23. Luh, L.-S.; Liu, L.-K. (h5-C5H5)-ring alkylation reaction with the C5H5 anion: Towards the construction of tri-Fe complex Fe{[m,h5:h4-5-exo-(1'-C5H4)C5H5]Fe(CO)2(PPh3)}2. J. Organomet. Chem. 2001, 637, 549-557.

  24. Luh, L.-S.; Wen, Y.-S.; Vanko, G.; Liu, L.-K. Ferrocenediyl-Bridged Tri-Iron Complexes. Organometallics 2001, 20, 2198.

  25. Adeyemi, O. G.; Liu, L.-K.; Wen, Y.-S. Reactions of (h5-C5H5)Fe(CO)2I with BuLi in the Presence of Arylpyridylphosphines. Crystal Structures of (h4-BuC5H5)Fe(CO)2PPh3-nPyn (n = 1 and 2). AJST 2000, 1, 396.

  26. Liu, H.; Jiang, C.; Yeo, J. S. L.; Mok, K. F.; Liu, L.-K.; Hor, T. S. A.; Yan, Y. K. Reactions of [Pt2(m-S)2(PPh3)4] With Group 6 and 7 Metal Carbonyls: Crystal Structure of the Apparently Unsaturated Heterometallic Complexes [Pt2Re(m3-S)2(PPh3)4(CO)3+]. J. Organomet. Chem. 2000, 595, 276.

  27. Eke, U. B.; Liao, Y.-H.; Wen, Y.-S.; Liu, L.-K. Stoichiometric vs Catalytic MeLi Reaction with the Mixture of (h5-C5H5)Fe(CO)2I and P(OR)3: Nucleophilic Methylation vs Arbuzov-like Dealkylation. J. Chin. Chem. Soc. 2000, 47, 109.

  28. Liu, L.-K.; Luh, L.-S. The Deprotonation Pathway in Me3SiSiMe3 Reaction with MeLi. Organometallics 2000, 19, 374.

  29. Jiang, C.; Wen, Y.-S.; Liu, L.-K.; Hor, T. S. A.; Yan, Y. K. Rhenium(I) Methoxo Carbonyl Complexes Containing Tetraphosphine or Triphosphine Ligands: Facile Separation and X-ray Crystallographic Studies of d/l and meso-[{Re2(m-OMe)2(CO)6}2(m,m'-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane)]. J. Organomet. Chem. 1999, 590, 138.
  30. Liu, L.-K. Electron Transfer Chain Catalysis. Bull. Inst. Chem., Academia Sinica 1999, 46, 31.

  31. Liu, L.-K.; Liao, Y.-H.; Eke, U. B. MeLi Reactions with the Electrophile System of (h5-C5H5)Fe(CO)2I/P(OMe)3: The Roles of MeLi as Reductant, Nucleophile, and Base. Organometallics 1999, 18, 1154.

  32. Hwang, W.-S.; Wang, D.-L.; Hsu, S.-T's.; Liu, L.-K. Silver(I) Complexes of Schiff Bases Derived from Thiophene-2,5-dicarboxaldehyde and Furan-2,5-dicarboxaldehyde. J. Chin. Chem. Soc. 1998, 45, 269.

  33. Peng, J.; Liu, L.-K. Phosphine-Exchange Induced Intramolecular Substitution Reaction of [{h5-C5H5}Fe(CO)2]2(m-h5:h5-PPh2CH2CH2PPh2)2+][PF6-]2. Bull. Inst. Chem., Academia Sinica 1998, 45, 27.

  34. Liu, L.-K.; Chang, K.-Y.; Wen, Y.-S. Anion-induced Migration Reaction of Acetylide From Iron to Cyclopentadienyl in (Cyclopentadienyl)irondicarbonyl(acetylide) Complexes. J. Chem. Soc., Dalton Trans. 1998, 741.

  35. Fu, Y.-T.; Chao, P.-C.; Liu, L.-K. Ring Opening of (Spiro[2.4]hepta-4,6-diene)tricarbonyliron: A Revisit. Organometallics 1998, 17, 221.

  36. Jiang, C.; Wen, Y.-S.; Liu, L.-K.; Hor, T. S. A.; Yan, Y. K. Controlled Acidolysis of Hexacarbonyltris(m-alkoxo)dirhenium(I) Anions: Facile Synthesis of Hexacarbonylbis(m-alkoxo)[m-1,1'-bis(diphenylphosphino)ferrocene]dirhenium(I) Complexes and Nonacarbonyltris(m-methoxo)(m3-methoxo)trirhenium(I). Organometallics 1998, 17, 173.

  37. Lin, C.-J.; Chen, Y.-H.; Lin, S.; Wen, Y.-S.; Liu, L.-K. Synthesis and Characterization of Dinuclear p-, m- and o-Xylyl Bridged Complexes of Molybdenum and Tungsten. The Crystal Structures of m-p-Xylyl-bis(h5-pentamethylcyclopentadienyltricarbonylmolybdenum) and m-m-Xylyl-bis(h5-pentamethylcyclopentadienyltricarbonyltungsten). Polyhedron 1997, 16, 4363.

  38. Jiang, C.; Wen, Y.-S.; Liu, L.-K.; Hor, T. S. A.; Yan, Y. K. Amine-oxide Mediated Reactions of Re2(CO)10 With Phenol and Aliphatic Alcohols: The Formation of Re3(CO)14(m-H) and a Hydroxo-methoxo Trirhenium Aggregate [Me3NH+][Re3(CO)9](m-OH)2(m-OMe)(m3-OMe)]-. J. Organomet. Chem. 1997, 543, 179.

  39. Fu, Y.-T.; Liu, L.-K. Preparation and Structural Study of Restricted Iron-Aminocarbene Complex [(CO)2Fe=C(NEt2)CH2CH2(h5-C5H4)+][BF4-]. Bull. Inst. Chem., Academia Sinica 1997, 44, 7.

  40. Feng, D.-F.; Tang, S. S.; Liu, C.-W.; Lin, I. J. B.; Wen, Y.-S.; Liu, L.-K. Synthesis and Characterization of Sulfur-Ylide Complexes of Gold(I). Observance of Intermolecular Gold(I)-Gold(I) Interactions in Solution. Organometallics 1997, 16, 901.

  41. Liu, L.-K.; Chang, K.-Y.; Wen, Y.-S. The Diphenylacetylene Reaction with Tricarbonylbis(h2-cis-cyclooctene)iron in the Presence or Absence of Carbon Monoxide. J. Chinese Chem. Soc. 1997, 44, 33.

  42. Liu, C.-W.; Wen, Y.-S.; Liu, L.-K. Neighboring Metal Induced Oxidative Addition in Conjunction With a Hydride Trap: The Formation of [(h5-MeC5H4)Fe(CO)(m-h1:h1-PPh2CH2PPh2)(m-H)M(CO)4], M = W, Mo. Organometallics 1997, 16, 155.

  43. Lin, S.; Lin, C.-J.; Wen, Y.-S.; Liu, L.-K. Synthesis and Characterization of Bis(triphenylphosphine)(ketone)copper and Bis(triphenylphosphine)bis(ketone)copper complexes: Crystal Structure of Bis(triphenylphosphine)bis(phenalenone)copper Tetrafluoroborate. Inorg. Chim. Acta. 1997, 256, 35.

  44. Liu, L.-K.; Luh, L.-S. Consecutive Butylations on the Cyclopentadienyl Ring of the [(h5-C5H5)Fe(CO)2PPh3]+ Cation. Organometallics 1996, 15, 5263.

  45. Hung, J.-T.; Kumaresan, S.; Lin, L.-C.; Wen, Y.-S.; Liu, L.-K.; Hwu, J. R. Reactions of 1-Hydroxypyridine-2-thione With Triosmium Clusters. Preparation and Transformation of N-Oxide-Containing Osmium Complexes. Organometallics 1996, 15, 5605.

  46. Gipson, S. L.; Liu, L.-K.; Soliz, R. U. The Reaction of CpFe(CO)2X (X = Cl, Br, I) With Phosphines Catalyzed by [CpFe(CO)2]2: Evidence for an Electron Transfer Chain Catalysis Mechanism.
    J. Organomet. Chem. 1996, 526, 393.

  47. Lin, S.; Liu, L.-K.; Wang, N.-T.; Wu, H.-Y. Synthesis and Characterization of Dinuclear m- and o-Xylene Bridged Complexes of Cyclopentadienyltricarbonylmolybdenum and Their Derivatives. The Crystal Structure of Bis(methylcyclopentadienyltricarbonyl-molybdenum)-a,a'-m-o-xylene. J. Organomet. Chem. 1996, 516, 207.

  48. Luh, L.-S.; Liu, L.-K. Structural Chemistry of the Multiply Butylated Cyclopentadiene Transition-Metal Complexes: X-ray Crystal Structures of Polybutylcyclopentadienedicarbonyltriphenyl-phosphineiron. Bull. Inst. Chem., Academia Sinica 1996, 43, 39.

  49. Low, P. M. N.; Tan, A. L.; Hor, T. S. A.; Wen, Y.-S.; Liu, L.-K.Substituted Metal Carbonyls. 27. Synthesis, Structures, and Metal-Metal Bonding of a Ferrocenylphosphine exo-Bridged Cluster with Two Heterometallic Triangles, [AuMn2(CO)8(m-PPh2)]2(m-dppf), and a Twisted-Bowtie Cluster, PPN+[AuMn2(CO)8(m-PPh2)]2- (dppf = 1,1'-Bis(diphenylphosphino)ferrocene). Organometallics 1996, 15, 2595.

  50. Low, P. M. N.; Yong, Y. L.; Yan, Y. K.; Hor, T. S. A.; Lam, S.-L.; Chan, K. K.; Wu, C.; Au-Yeung, S. C. F.; Wen, Y.-S.; Liu, L.-K. Substituted Metal Carbonyls. 26. One-Step Synthesis, Structures, NMR, and Dynamic Laser-Light Scattering of Re2(m-OMe)2[m-Ph2P(CH2)nPPh2](CO)6 (n = 1-4). Organometallics 1996, 15, 1369.

  51. Liu, L.-K.; Luh, L.-S.; Wen, Y.-S.; Eke, U. B.; Adediran Mesubi, M. Synthesis of Heterobimetallic Complexes From (h4-MeC5H5)Fe(CO)2(h1-PPh2CH2PPh2). Organometallics 1995, 14, 4474.

  52. Liu, L.-K.; Eke, U. B.; Adediran Mesubi, M. Synthesis of Half-Sandwich Iron Carboxyalkyls and Iron(Thiocarboxy) alkyls: Reaction of Cyclopentadienyldicarbonyliodoiron With O- and S-Based Nucleophiles in the Presence of Triphenylphosphine. Organometallics 1995, 14, 3958.

  53. Liu, L.-K.; Luh, L.-S.; Chao, P.-C.; Fu, Y.-T. A Study on the Three-component Reactions of Cyclopentadienyldicarbonyliodoiron or Indenyldicarbonyliodoiron With Methyllithium in the Presence of Triphenylphosphine. Bull. Inst. Chem., Academia Sinica 1995, 42, 1.

  54. Luh, L.-S.; Liu, L.-K. Synthesis and X-ray Strucutre of [(h5-C5H5)Fe(CO)C(O)Me](m-h1:h1-dppe)[(h4-exo-MeC5H5 )Fe(CO)2]. Organometallics 1995, 14, 1514.

  55. Luh, L.-S.; Eke, U. B.; Liu, L.-K. Cyclopentadienyldicarbonyliron Halides as Electrophiles: Reactions of (h5-C5H5)Fe(CO)2I with MeLi in the Presence of Monophosphines and Diphosphines.
    Organometallics 1995, 14, 440.

  56. Liu, L.-K; Luh, L.-S. Cyclopentadienyldicarbonyliron Halides as Electrophiles: A Study on the Reactions of CpFe(CO)2X with PhLi in the Presence of PPh3 to Produce (PhC5H5)Fe(CO)2(PPh3) and (C5H5)Fe(CO)(PPh3)C(O)Ph. Bull. Inst. Chem., Academia Sinica 1994, 41, 39.

  57. Liu, L.-K; Luh, L.-S. Cyclopentadienyldicarbonyliron Halides as Electrophiles: The Reactions of (h5-C5H5)Fe(CO)2X with RLi in the Presence of PPh3 to Produce (h4-exo-RC5H5)-Fe(CO)2(PPh3) and the Preparation of [(h5-C5H5)Fe(CO)C(O)Me](m-h1:h1-dppf)[(h4-exo-MeC5H5) Fe(CO)2]. Organometallics 1994, 13, 2816.

Update： 2010-02-06

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