Shyu, Shin-Guang

Organometallic Chemistry, Materials Chemistry

Shyu, Shin-Guang (徐新光)

    886-2-27898592
    886-2-27831237
    sgshyu
Deputy Director(2012-2013);Research Fellow (1996-);B.S., National Cheng Kung University (1978);Ph.D., Inorganic Chemistry, The Ohio State University, USA (1986);Postdoctoral Research Fellow, University of Illinois at Urbana-Champaign, USA (1986-88);Assistant Scientist, Brookhaven National Laboratory, USA (1988- 90);Associate Research Felloww, Academia Sinica (1990-96) ;
Research Interests

Organometallic Chemistry: Role of metal-metal bond in the chemistry of bimetallic complexes; Cu homogeneous catalysis in cross coupling reactions
Inorganic materials: Preparation of thermal electric composite materials.



Selected Publications
  1. Chen, H.-J.; Hsu, I-J.; Tseng, M.-C.; Shyu, S.-G. Possible Intermediates of Cu(Phen)-catalyzed C-O cross coupling of phenol with aryl bromide by in situ ESI-MS and EPR studies. Dalton 2014, accepted
  2. Hossain, Md. M.; Huang, W.-K.; chen, H.-J.; Wang, P.-H.; Shyu, S.-G. Efficient and selective copper-catalyzed organic solvent-free and biphasic oxidation of aromatic gem-disubstituted alkenes to carbonyl compounds by tert-butyl hydroperoxide at room temperature. Green Chemistry 2014, 6937.
  3. Tseng, C.-K.; Lee, C.-R.; Tseng, M.-C.; Han, C.-C.; Shyu, S.-G. Reactivity of [K3(phen)8][Cu(NPh2)2]3-A Possible Intermediate in the Copper(I)-Catalyzed N-Arylation of N-Phenylaniline. Dalton 2014, 6937-7332. (DOI: 10.1039/C4DT00051J, selected as a Dalton Transactions Hot Article and highlighted in the inner cover for the issue)
  4. Hossain, Md. M; Shyu, S.-G. Selective copper(II)-catalyzed aerobic oxidative cleavage of aromatic gem-disubstituted alkenes to carbonyl compounds under neutral and mild conditions. Tetrahedron 2014, 251.
  5. Hossain, Md. M; Shyu, S.-G. Synthesis, Structure and Reactivity of [Cu(phen)2]ClO2-Aerobic Oxidation of Cl- to ClO2- at Room Temperature. Eur. J. Inorg. Chem. 2014, 36.
  6. Lan, T.-W. ; Chen, Y.-C.; Ho, J.-C.; Shyu, S.-G.; Chen, Y.-Y. Thermoelectric Figure of Merit Enhancement in Bi2Te3-Coated Bi Composites. J. Electron. Mater2012, 41, 2326.
  7. Shyu, S.-G.; Tseng, C.-K.; Chen, H.-P.; Liu, H.-C.; Twu, J. Effect of Metal Salen in the Base Catalyzed Catalytic Reaction between Carbon Dioxide and Epoxides. J. Chin. Chem. Soc. 2012, 59, 443.
  8. Chang, H.-Y.; Wang, S.-P.; Chang, J.-R.; Sheu, H.–S.; Shyu, S.-G. Synchrotron Radiation PXRD investigation of V2O5/TiO2 catalysts for 1,2-dichlorobenzene oxidation: implication of structure. Appl. Catal. B: Environ. 2012, 111, 476.
  9. Tseng, C.-K.; Tseng, M.-C.; Han, C.-C.; Shyu, S.-G. A Copper (II) Complex as an Intermediate of Copper(I)-Catalyzed C-N Cross Coupling of N-Phenylaniline with Aryl Halide by in situ ESI-MS Study. Chem. Commun. 2011, 47, 6686.
  10. Cheng, S.-W.; Tseng, M.-C.; Lee, C.-R.; Shyu, S.-G. Intermediates of Copper(I)-Catalyzed C-S Cross Coupling of Thiophenol with Aryl Halide by in situ ESI-MS study. Chem. Commun. 2011,  47, 5599.
  11. Tseng, C.-K.; Lee, C.-R.; Han, C.-C.; Shyu, S.-G. Copper(I) Anilide Complex [Na(phen)3][Cu(NPh2)2]-an Intermediate of Copper-Catalyzed N-Arylation of N-Phenylaniline Reaction. Chem. Eur. J. 2011, 17, 2716.
  12. Hossain, Md. M.; Shyu, S.-G. Efficient and Selective Aerobic Alcohol Oxidation Catalyzed by Copper(II)/2,2,6,6,-Tetramethylpiperidine-1- oxyl at Room Temperature. Adv. Synth. Catal. 2010, 352, 3061-3068.
  13. Chang, J.-R.; Lin, H.-M.; Cheng, S.-W.; Tseng, C.-K.; Tzou, D.-L.; Shyu, S.-G. EXAFS investigation of the morphology of immobilized Rh(PPh3)3Cl on phosphinated MCM-41. J. Mol. Catal. A: Chem. 2010, 329, 27.
  14. Lin, H.-M.; Wang, W.-K.; Shyu, S.-G. Light-sensitive intelligent drug delivery systems of coumarin-modified mesoporous bioactive glass. Acta Biomaterialia. 2010, 6, 3256.
  15. Sheu, H.-S.; Lee, J.-F.; Shyu, S.-G.; Chou, W.-W.; Chang, J.-R. Sulfur resistance enhancement by grafted TiO2 in SiO2-supported Pd catalysts:Role of grafted TiO2 and genesis of Pd clusters. J. Catal., 2009, 266, 15.
  16. Lin, L. K.; Chi, Y. S.; Chen, T. M.; Shyu, S. G.; Huang, J. H.; Lee, S. F. Superconducting and magnetic properties of Ni/Pb multilayered nanowires. J. Appl. Phys. 2009, 105, 07D519.
  17. Hossain, Md..M.; Lin, H.-M.; Wang, C.-M.; Shyu, S.-G. Synthesis and Characterization of Single Thiolato-Bridged Heterodinuclear Complexes: Irreversible Isomerization of Cp(CO)2W(m-SPh)(m-Cl)Ru(CO) (Cl)(PPh3) to Cp(CO)(Cl)W(m-SPh)(m-Cl)Ru(CO)2(PPh3) via Chloride and Carbonyl Ligands Migration. Organometallics 2009, 28, 264.
  18. Lin, Y.-C.; Chang, C.-H.; Chen, C.-C.; Jehng, J.-M.; Shyu, S.-G. Supported vanadium oxide catalysts in selective oxidation of ethanol: comparison of TiO2/SiO2 and ZrO2/SiO2 as supports. Catal. Commun. 2008, 9, 675.
  19. Cheng, C. Y.; Lin, K. –J.; Prasad, M. R.; Fu, S. –J.; Chang, S. –Y.; Shyu, S. –G.; Sheu, H. –S.; Chen, C. –H.; Chuang, C. –H.; Lin, M. –T. Synthesis of a reusable oxotungsten-containing SBA-15 mesoporous catalyst for the organic solvent-free conversion of cyclohexene to adipic acid. Catal. Commun. 2007, 8, 1060.
  20. Hossain, Md. M.; Lin, H.-M.; Shyu, S.-G. Formation of a Dithiophosphinate Ligand Ph2PS2 by Sulfur Insertion into the Metal—Phosphido Bond on Heterobimetallic Phosphido-Bridged Complex Cp(CO)2W(m-PPh2)Mo(CO)5 : a Rare Example of Neutral Six-Electron Mixed-Metal Cluster with a Mo2WS4 Core. Organometallics 2007, 25, 685.
  21. Hossain, Md. M.; Lin, H.-M.; Chu, J.; Lin, Z.; Shyu, S.-G. Activation of the S-S Bonds of Alkyl Disulfides RSSR (R = Me, Et, Pr, Bun) on Heterodinuclear Phosphido-Bridged CpW(CO)2(m-PPh2)Mo(CO)5. Organometallics 2006, 25, 440.
  22. Neeleshwar, S.; Chen, C. L.; Tsai, C. B.; Chen, Y. Y.; Chen, C. C.; Shyu, S.-G.; Seehra, M.S. Size-dependent properties of EdSe quantum dots. Phys. Rew. B 2005, 71, 201307
  23. Chang, C. F.; Huang, D. J.; Tanaka, A.; Guo, G. Y.; Chung, S. C.; Kao, S. T.; Shyu, S.-G.; Chen, C. T. Electronic Structure of CrO2 Studied by Magnetic Circular Dichroism in Resonant Photoemission. Phys. Rew. B, 2005, 71 052407.
  24. Hossain, Md. M.; Lin, H.-M.; Shyu, S.-G. Reaction of CpW(CO)2(m-PPh2)Mo(CO)5 and Fe2(m-S2)(CO)6— Unusual Fragmentation and Coordination of Fe2(m-S2)(CO)6. Organometallics 2004, 23, 3941-3949.
  25. Lin, H.-M.; Chang, J.-R.; Kao, S.-T.; Lin, K.-M.; Shyu, S.-G. Grafting TiO2 on MCM-41 as a TiO2 Support for Vanadia for Catalytic Oxidation of Ethanol-EXAFS and XANES Analysis of Vanadium. J. Catal. 2004, 224, 156-163.
  26. Hossain, Md. M.; Lin, H.-M.; Shyu, S.-G. Thiolate Ligand Transfer from Metallothiolates to Phosphido- Bridged Heterobimetallic Compound: C-S Bond Cleavage in Benzenethiol and Formation of a Mixed Metal Trinuclear Compound. Organometallics 2003, 22, 3262-3270.
  27. Huang, D.-J.; Tjeng, L. H.; Chen, J.; Chang, C.-F.; Wu, G.-Y.; Chung, S.-C.; Tanaka, A.; Guo, G. Y.; Lin, H.-J.; Shyu, S.-G.; Wu, C.-C.; Chen, C. T. Anamalous spin polarization and dualistic electronic nature of CrO2. Phys. Rew. B 2003, 67 214419.
  28. Huang, D.-J.; Tjeng, L. H.; Chang, C.-F.; Guo, G.-Y.; Chen, J.; Wu, W.-P.; Chung, S.-C.; Shyu, S.-G.; Wu, C.-C.; Lin, H.-J.; Chen, C. T. Orbital magnetic moments of oxygen and chromium in CrO2. Phys. Rew. B 2002, 66 174440.
  29. Fu, C. M.; Lai, C. J.; Hsu, H. S.; Chao, Y. C.; Huang, J. C. A.; Wu, C. -C.; Shyu, S.-G Characterization of magneto-impedance on polycrystalline and amorphous chromium oxides bi-layered thin films. J. Appl. Phys. 2002, 91 (10): 7143-7145.
  30. Shyu, S.-G.; Singh, R.; Su, C.-J.; Lin, K.-J. Elecrtrophilic-Site Switching in Phosphindo-Bridged Bimetallic Complex via Metal-metal bond Formation. Eur. J. Inorg. Chem. 2002, 1343.
  31. Shyu, S.-G.; Wu, J.-S.; Wu, C.-C.; Chuang, S.-H.; Chi, K.-M. Iron Sulfide Films via Fe2(CO)6(m-S2) as a MOCVD Single Source Precursor. Inorg. Chim. Acta. 2002, 334c, 276-282.
  32. Fu, C. M.; Lai, C. J.; Wu, J. S.; Huang, J. C. A.; Wu, C.-C.; Shyu, S.-G. High frequency impedance spectra on the chromium dioxide thin film. J. Appl. Phys. 2001, 89 (11): 7702-7704.
  33. Hossain, Md. M.; Lin, H.-M.; Shyu, S.-G. Synthesis and Structure of Heterobimetallic Compounds with a Single Thiolato-Bridged Ligand. Eur. J. Inorg. Chem. 2001, 2655.
  34. Shyu, S.-G.; Chen, S.-W.; Tzou, D.-L. Immobilization of Rh(PPh3)3Cl on phosphinated MCM-41 for catalytic hydrogenation of olefins. J. Chem. Soc. Chem. Commun. 1999, 2337.
  35. Shyu, S.-G.; Wu, J.-S.; Sung, Y.-S.; Chi, K.-M. Preparation of tungsten Cobalt Carbides and Oxide via an Organometallic Heterobimetallic Complex as a Single Source Precursor. J. Am. Ceram. Soc. 1999, 82, 1436-1440.
  36. Shyu, S.-G.; Singh, R.; Lin, K.-J. Synthesis of Bimetallic Phosphido-Bridged Isocyanide M-Mo (M = Mo, W) complexes. Organometallics 1998, 17, 4739-4743.
  37. Hsiao, S.-M.; Shyu, S.-G.; Bond, M.-M. Assisted Substitution Reaction of Heterobimetallic Phosphido-bridged Mo-Fe Complex. Organometallics 1998, 17, 1151-1155.
  38. Fogg, A. M.; Dunn, J. S.; Shyu, S.-G.; Carey, D. R.; O'Hare, D. Selective Ion-Exchange Intercalation of Isomeric Dicarbonxylate Anions into the Layered Double Hydroxide [LiAl2(OH)6]Cl2.H2O. Chem. Mater. 1998, 10, 351.
  39. Shyu, S.-G.; Wu, J.-S.; Chuang, S.-H.; Chi, K.-M.; Sung, Y.-S. Mixed Metal Oxide Films via Heterobimetallic Complex as a MOCVD Single Source Precursor. J. Chem. Soc. Chem. Commun. 1996, 2239.

Update: 2015-03-23

Journal Paper
  1. 1. Md. Munkir Hossain, Wei-Kai Huang, Hung-Jie chen, Pei-Han Wang and Shin-Guang Shyu* Efficient and selective copper-catalyzed organic solvent-free and biphasic oxidation of aromatic gem-disubstituted alkenes to carbonyl compounds by tert-butyl hydroperoxide at room temperature. Green Chemistry 2014, .
  2. Chia-Kai Tseng, Chi-Rung Lee, Mei-Chun Tseng, Chien-Chung Han and Shin-Guang Shyu* Reactivity of [K3(phen)8][Cu(NPh2)2]3-A Possible Intermediate in the Copper(I)-Catalyzed N-Arylation of N-Phenylaniline. Dalton Transactions 201419(43), 6937-7332.
  3. Md. Munkir Hossain and Shin-Guang Shyu* Selective copper(II)-catalyzed aerobic oxidative cleavage of aromatic gem-disubstituted alkenes to carbonyl compounds under neutral and mild conditions. Tetrahedron 2014, 251-255.
  4. Md. Munkir Hossain, Chi-Rung Lee and Shin-Guang Shyu* Synthesis, Structure and Reactivity of [Cu(phen)2]ClO2-Aerobic Oxidation of Cl to ClO2 at Room Temperature. Eur. J. Inorg. Chem. 2014, 36-40.
  5. T. W. Lan, Y. C. Chen, J. C. Ho, S. G. Shyu*, Y. Y. Chen* Thermoelectric Figure of Merit Enhancement in Bi2Te3-Coated Bi Composites. JOURNAL OF ELECTRONIC MATERIALS 2012-09, 41 2326-2330.
  6. Shin-Guang Shyu*, Chia-Kai Tseng, Hung-Po Chen, Hsin-Chih Liu, and Jen Twu Effect of Metal Salen in the Base Catalyzed Catalytic Reaction between Carbon Dioxide and Epoxides. J. Chin. Chem. Soc. 2012-05, 59 443-451.
  7. Hsi-Yan Chang, Shiu-Ping Wang, Jen-Ray Chang, Hwo–Shuenn Sheu*, Shin-Guang Shyu* Synchrotron Radiation PXRD investigation of V2O5/TiO2 catalysts for 1,2-dichlorobenzene oxidation: implication of structure. APPLIED CATALYSIS B-ENVIRONMENTAL 2012111-112, 476-484.
  8. Chia-Kai Tseng, Mei-Chun Tseng, Chien-Chung Han* and Shin-Guang Shyu* A Copper (II) Complex as an Intermediate of Copper(I)-Catalyzed C-N Cross Coupling of N-Phenylaniline with Aryl Halide by in situ ESI-MS Study. Chem. Commun. 2011-0647 (23), 6686 – 6688..
  9. Wei-Lin Su, Hsiu-Ping Huang, Wei-Ting Chen, Wen-Yi Hsu, Hsi-Yen Chang, Szu-Yu Ho, Shao-Pin Wang*, Shin-Guang Shyu* Natural Bond Orbital Rationalizations of NMR Observations for Metal-Ligand Bonding (II): Rehybridization of Phosphorus Arising from Coordination of Methyl-Phenyl-Phosphines. J. Chin. Chem. Soc. 2011-0658, 163-173.
  10. Shao-Wen Cheng, Mei-Chun Tseng, Chi-Rung Lee and Shin-Guang Shyu* Intermediates of Copper(I)-Catalyzed C-S Cross Coupling of Thiophenol with Aryl Halide by in situ ESI-MS study. Chem. Commun. 2011-0447 (19), 5599 – 5601.
  11. Chia-Kai Tseng, Chi-Rung Lee, Chien-Chung Han and Shin-Guang Shyu* Copper(I) Anilide Complex [Na(phen)3][Cu(NPh2)2]-an Intermediate of Copper-Catalyzed N-Arylation of N-Phenylaniline Reaction. CHEMISTRY-A EUROPEAN JOURNAL 2011-0217, 2716-2723.
  12. Md. Munkir Hossain, Shin-Guang Shyu Efficient and Selective Aerobic Alcohol Oxidation Catalyzed by Copper(II)/2,2,6,6-Tetramethylpiperidine-1- oxyl at Room Temperature. ADVANCED SYNTHESIS & CATALYSIS 2010-12352, 3061-3068.
  13. Jen-Ray Chang, Hsiu-Mei Lin, Sheau-Wen Cheng, Chia-Kai Tseng, Der-Lii Tzou, Shin-Guang. Shyu EXAFS investigation of the morphology of immobilized Rh(PPh3)3Cl on phosphinated MCM-41. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 2010-08329, 27-35.
  14. H.-M. Lin, W. -K Wang, S.-G. Shyu Light-sensitive intelligent drug delivery systems of coumarin-modified mesoporous bioactive glass. Acta Biomaterialia 2010-086, 3256-3263.
  15. Hwo-Shuenn Sheu, Jyh-Fu Lee, Shin-Guang Shyu, Wha-Wen Chou, Jen-Ray Chang Sulfur resistance enhancement by grafted TiO2 in SiO2-supported Pd catalysts:Role of grafted TiO2 and genesis of Pd clusters. Journal of Catalysis 2009-08, 266(1) 15-25.
  16. L. K. Lin,Y. S. Chi, T. M. Chen, S. G. Shyu, J. H. Huang, and S. F. Lee Superconducting and magnetic properties of Ni/Pb multilayered nanowires. J. Appl. Phys. 2009-04105(7), 07D519.
  17. Md. Munkir Hossain, Hsiu-Mei Lin, Chih-Min Wang, Shin-Guang Shyu*  Synthesis and Characterization of Single Thiolato-Bridged Heterodinuclear Complexes: Irreversible Isomerization of Cp(CO)2W(mu-SPh)(mu-Cl)Ru(CO)(Cl)(PPh3) to Cp(CO)(Cl)W(mu-SPh)(mu-Cl)Ru(CO)2(PPh3) via Chloride and Carbonyl Ligands Migration. Organometallics 2009-01,  28 (1) 264-269.
  18. 2. Yu-Chuan Lin, Chih-Hung Chang, Chih-Chen Chen, Jih-Mirn Jehng, Shin-Guang Shyu Supported vanadium oxide catalysts in selective oxidation of ethanol: comparison of TiO2/SiO2 and ZrO2/SiO2 as supports. Catal. Commun 20089, 675.
  19. 3. C. Y. Cheng, K. –J. Lin*, M. R. Prasad, S. -J Fu, S. –Y Chang, S. –G Shyu, H. –S. Sheu, C. –H Chen, C. –H Chuang, M. –T Lin Synthesis of a reusable oxotungsten-containing SBA-15 mesoporous catalyst for the organic solvent-free conversion of cyclohexene to adipic acid. Catal. Commun. 2007-88, 1060.
  20. Md. Munkir Hossain, Hsiu-Mei Lin, Shin-Guang Shyu Formation of a Dithiophosphinate Ligand Ph2PS2 by Sulfur Insertion into the Metal−Phosphido Bond on Heterobimetallic Phosphido−Bridged Complex Cp(CO)2W(μ-PPh2)Mo(CO)5 : a Rare Example of Neutral Six−Electron Mixed−Metal Cluster with a Mo2WS4 Core. Organometallics 200725, 685.
  21. Hossain, MM, Lin, HM, Zhu, J, Lin, ZY and Shyu, SG Activation of the S-S bonds of alkyl disulfides RSSR (R = Me, Et, Pr, Bu-n) by heterodinuclear phosphido-bridged CpW(Co)(2)(mu-PPh2)Mo(CO)(5). ORGANOMETALLICS 2006-0125(2), 440-446.
  22. C.F. Chang, D.J. Huang*, A. Tanaka, G.Y. Guo, S.C. Chung, S.T. Kao, S.G. Shyu and C.T. Chen Electronic structure of CrO2 studied by magnetic circular dichroism in resonant photoemission.. PHYSICAL REVIEW B 200571, 52407-0.
  23. S Neeleshwar, C.L. Chen, C.B. Tsai, Y.Y. Chen*, C.C. Chen, S.G. Shyu and M.S. Seehra Size-dependent properties of EdSe quantum dots.. PHYSICAL REVIEW B 200571(20), 201307-0.
  24. H.-M. Lin, J.-R. Chang, S.-T. Kao, K.-M. Lin and S.-G. Shyu* Grafting TiO2 on MCM-41 as a TiO2 support for vanadia for catalytic oxidation of ethanol EXAFS and XANES analysis of vanadium.. J. Catal. 2004224, 156-163.
  25. D.J. Huang*, C.F. Chang, J. Chen, H.J. Lin, S.C. Chung, H.T. Jeng, G.Y. Guo, W.B. Wu, S.G. Shyu and C.T. Chen Orbital moments of CrO2 and Fe3O4 studied by MCD in soft X-ray absorption.. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA 2004137-40(Sp. Iss. SI JUL), 633-639.
  26. M.M. Hossain, H.-M. Lin and S.-G. Shyu* Reaction of CpW(CO)2((-PPh2)Mo(CO)5 and Fe2((-S2)(CO)6 Unusual fragmentation and coordination of Fe2((-S2)(CO)6.. Organometallics 200423, 3941-3949.
  27. D.-J. Huang*, L. H. Tjeng, J. Chen, C.-F. Chang, G.-Y. Wu, S.-C. Chung, A. Tanaka, G. Y. Guo, H.-J. Lin, S.-G. Shyu, C.-C. Wu and C.T. Chen Anamalous spin polarization and dualistic electronic nature of CrO2.. PHYSICAL REVIEW B 2003, 67(214419).
  28. M.M. Hossain, H.-M. Lin and S.-G. Shyu* Thiolate ligand transfer from metallothiolates to phosphido- bridged heterobimetallic compound: C-S bond cleavage in benzenethiol and formation of a mixed metal trinuclear compound.. Organometallics 200322, 3262-3270.