Isorecticular Synthesis of Dissectible Molecular Bamboo Tubes of Hexarhenium(I) Benzene-1,2,3,4,5,6-hexaolate Complexes
竹節狀金屬有機奈米管

Angew. Chem. Int. Ed. 2016, 55, 8343-8347. (Cover Picture (Back Cover))
Tien-Wen Tseng, Tzuoo-Tsair Luo, Shi-Hao Liao, Kai-Hsiang Lu, and Kuang-Lieh Lu

The Star of David …… is the structural motif of important doubly tri-legged structures that can be stacked together by applying lock-and-key strategies. This Communication show how this approach can lead to the systematic construction of dissectible bamboo-like metal organic tubes (resembling the form of the tower Taipei 101)

Isorecticular Synthesis of Dissectible Molecular Bamboo Tubes of Hexarhenium(I) Benzene-1,2,3,4,5,6-hexaolate Complexes

竹節狀金屬有機奈米管之自組裝如鎖鑰般具可逆性。其建構單元六錸金屬苯環六氧基之結構與配位型態,在有機、無機化學文獻中未曾見過。