中央研究院化學研究所－人員

運用與操作X光單晶繞射儀協助使用者進行化學合成相關研究。
分子結構解析與鑑定。
變型電子密度研究。

• The service statistics of laboratory at Academia Sinica since year 2010 is listed in Figure 1. The number of annual laboratory service include other three different Institute at Sinica.
  
  
  
• From 2010 to 2015, the Service Performance of sample for sample number and machine total service time list in Figure 2 and Table 1.
  
  
  
  

1. Tigineh, G. T.; Wen, Y.-S.; Liu, L.-K. Solvent-free mechanochemical conversion of 3-ethoxysalicylaldehyde and primary aromatic amines to corresponding Schiff-bases. Tetrahedron, 2015, 71, 170.
2. Gajewska, M. J.; Ching, W.-M.; Wen, Y.-S.; Hung, C.-H. Synthesis, structure, and catecholase activity of bispyrazolylacetate copper(II) complexes. Dalton Trans., 2014, 43, 14726.
3. Watanabe, M.; Chien, C.-T.; Lin, Y.-D.; Chang, Y. J.; Wen, Y.-S.; Goto, K.; Shibahara, M.; Shinmyozu, T.; Chow, T. J. Synthesis, physical properties, and structure of TIPS-difuranoacenes. Tetrahedron Lett., 2014, 55, 1424.
4. Lu, N.; Hight, L. M.; McMillin, D. R.; Jhuo, J.-W.; Chung, W.-C.; Lin, K.-Y.; Wen, Y.-S.; Liu, L.-K. Structure and emission studies of dimorphic crystals of [PtBr2(5,5'-bis(CF3CH2OCH2)-2,2 '-bpy)]. Dalton Trans., 2014, 43, 2112.
5. Wang, W.-Z.; Duan, Y.-S.; Wang, J.-M.; Li, L.-C.; Liao, D.-Z.; Ismayilov, R. H.; Wen, Y.-S.; Lee, G.-H.; Peng, S.-M.; Zhu, Y.-Q. A 2-D Grid Coordination Polymer with an In-plane and Out-of-plane Structure Bridged by Pyrazine Spacers. J. Chin. Chem. Soc., 2013, 60, 699.
6. Sheu, C.-F.; Chen, S.-M.; Lee, G.-H.; Liu, Y.-H.; Wen, Y.-S.; Lee, J.-J.; Chuang, Y.-C.; Wang, Y. Structure and Magnetism of the Iron(III) Spin-Crossover Complex [Fe-III{N-ethyl-N-(2-aminoethyl)salicylaldiminate}(2)]ClO4. Eur. J. Inorg. Chem. 2013, 894.
7. Watanabe, M.; Su, W.-T.; Chang, Y. J.; Chao, T.-H.; Wen, Y.-S.; Chow, T. J. Solution-Processed Optoelectronic Properties of Functionalized Anthradifuran. Chem.-An Asian J. 2013, 8, 60.
8. Lin, G.-W.; Lin, Y.-C.; Lin, S.-C.; Wen, Y.-S.; Liu, L.-K. Ionic Liquid in Synthesis: A Phase Transfer Reagent and a Redox Mediating Medium. J. Chin. Chem. Soc. 2013, 60, 281.
9. Lin, Y.-D.; Pen, Y.-S.; Su, W.; Liau, K.-L.; Wen, Y.-S.; Tu, C.-H.; Sun, C.-H.; Chow, T. J. Reaction-Based Colorimetric and Ratiometric Fluorescence Sensor for Detection of Cyanide in Aqueous Media. Chem.-An Asian J. 2012, 7, 2864.
10. Chaurasia, S.; Chen, Y.-C.; Chou, H.-H.; Wen, Y.-S.; Lin, J. T. Coplanar indenofluorene-based organic dyes for dye-sensitized solar cells. Tetrahedron 2012, 68, 7755.
11. Lee, I-L.; Li, S.-R.; Chen, K.-F.; Ku, P.-J.; Singh, A. S.; Kuo, H.-T.; Wen, Y.-S.; Chu, C.-W.; Sun, S.-S. Synthesis, Photophysical Properties, and Field-Effect Characteristics of (Ethynylphenyl)benzimidazole-Decorated Anthracene and Perylene Bisimide Derivatives. Eur. J. Org. Chem. 2012,  2906.
12. Chen, Y.-C.; Chen, Y.-H.; Chou, H.-H.; Chaurasia, S.; Wen, Y. S.; Lin, J. T.; Yao, C.-F. Naphthyl and Thienyl Units as Bridges for Metal-Free Dye-Sensitized Solar Cells. Chem.-An Asian J. 2012, 7, 1074.
13. Chien, C.-T.; Lin, C.-C.; Watanabe, M.; Lin, Y.-D.; Chao, T.-H.; Chiang, T.-c.; Huang, X.-H.; Wen, Y.-S.; Tu, C.-H.; Sun, C.-H.; Chow, T. J. Tetracene-based field-effect transistors using solution processes. J. Mater. Chem. 2012, 22, 13070.
14. Wang, W.-Z.; Ismayilov, R. H.; Lee, G.-H.; Wen, Y.-S.; Peng, S.-M. Bis(morpholin-4-ium) tetrachloridocobalt(II). Acta  Cryst. E, 2011, 68, m51.
15. Lai, L.-L.; Yang, C.-M.; Liu, C.-C.; Cheng, K.-L.; Wen, Y.-S.; Hung, C.-H.; Luo, T.-T.; Kuo, M.-Y. Direct Evidence of a Liguid-Crystalline Phase Induced by Intermolecular C-H▪▪▪Cl Interactions on the Basis of IR Spectroscopy and Theoretical Simulations. Chem. Eur. J., 2011, 17, 111.
16. Huang, P.-H.; Lin, K.-L.; Wen, Y.-S. [4-(1-Benzofuran-2-yl)phenyl]diphenylamine. Acta Cryst. E, 2011, 67, o109.
17. Chen, K.-Y.; Wen, Y.-S.; Fang, T.-C.; Fang, Y.-J.; Chang, M.-J. 7-Hydroxyindan-1-one. Acta Cryst. E, 2011, 67, o927.
18. Datta, A.; Chuang, N.-T.; Wen, Y.-S.; Huang, J.-H.; Sheu, S.-C. {N'-[1-(2-Pyridyl)ethylidene-N]benzohydrazidato-    2N',O}{N'-[1-(2-pyridyl)ethylidene-N]benzohydrazide-2N',O}copper(II) trichloroacetate.” Acta Cryst. E, 2011, 67, m1388.
19. Huang, P.-H.; Lin, K.-L.; Wen, Y.-S. 2-(9,9-Diethyl-9H-fluoren-2-yl)-1-benzofuran. Acta Cryst. E. 2011, 67, o743.
20. Laxmansingh T P.; Wen, Y.-S.; Hung, S.-C. Metal trifluoromethanesulfonate-catalyzed regioselective acylation of myo-inositol 1,3,5-orthoformate. Chem Comm. 2010, 46, 5524.
21. Lu, N.; Tu, W. H.; Wu, Z. W.; Wen, Y. S.; Liu, L. 4,4'-Bis(2,2,2-trifluoroethoxymethyl)-2,2'-bipyridine. Acta Cryst C.  2010, C66(6), o289.
22. Lu, N.; Tu, W.-H.; Shing, J.-S.; Wen, Y.-S.; Liu, L.-K. New type of saccharinate crystals: A possible supramolecular synthon. J. Mol. Struct. 2010, 980(1-3), 101.
23. Lu, N.; Tu, W.-H.; Wen, Y.-S.; Liu, L.-K.; Chou, C.-Y.; Jiang, J.-C. The intramolecular blue-shifting C-HF-C hydrogen bond: crystal structure of [4,4'-bis(HCF2CF2CF2CF2CH2OCH2)-2,2'- bpy]MCl2 where M = Pt, Pd. CrystEngComm 2010, 12(2), 538.
24. Padiyar, L. T.; Wen, Y.-S.; Hung, S.-C. Metal Trifluromethanesulfonate-Catalyzed Regioselective Acylation of myo-Inositol Orthoformate. Chem. Commun., 46, 2010, 5524.
25. Chuang, C.-H.; Malaichamy S.; Tseng, Y.-H.; Wu, J.-Y.;  Hsu, K.-C.; Hung, C.-H.; Wen, Y.-S.; Lu, K.-L. A Rigidity-Modulated Approach toward the Construction of Metallacycles from a Flexible Tetratopic Ligand. Organomet. 2010, 29, 283.
26. Wu, J.-Y.; Ding, M.-T.; Wen, Y.-S.; Liu, Y.-H.; Lu, K.-L. Remarkable Alkali Cation (K+, Cs+)-Induced Dissolution/Reorganization of Porous Metal- Carboxylate Coordination Networks in Water. Chem. 2009, 15, 3604.
27. Luo, T. T.; Wu, H. C.; Jao, Y. C.; Huang, S. M.; Tseng, T. W.; Wen, Y. S.; Lee, G. H.; Peng, S. M.; Lu, K. L. Self-Assembled Arrays of Single-Walled Metal−Organic Nanotubes. Angew. Chem. Int. Ed. 2009, 48, 9461.
28. Wu, J. Y.; Ding, M. T.; Wen, Y. S.; Liu, Y. H.; Lu, K. L. Alkali Metal Cation (K+, Cs+) Induced Dissolution/Reorganization of Porous Metal Carboxylate Coordination Networks in Water. Chem. Eur. J. 2009, 15, 3604.
29. Wu, J. Y.; Hsu, H. Y.; Chan, C. C.; Wen, Y. S.; Tsai, C.; Lu, K. L. Formation of Infinite Linear Mercury Metal Chains Assisted by Face-to-Face π-π (Aryl-Aryl) Stacking Interactions. Cryst. Growth Des. 2009, 9, 258.
30. Singh, A. S.; Chen, B.-Y.; Wen, Y.-S.; Tsai, C.; Sun, S.-S. Halide Dependent Formation of Molecular Receptors and Their Ion Recognition Propertiesf. Org. Lett. 2009, 11, 1867.
31. Hung, C.-Y.; Singh, A. S.; Chen, C.-W; Wen, Y.-S.; Sun, S.-S. Colorimetric and Luminescent Sensing of F- Anion Through Strong Anion–p Interaction Inside the p-Acidic Cavity of A Pyridyl-Triazine Bridged Trinuclear Re(I)-Tricarbonyl Diimine Complex. Chem. Commun. 2009, 1511.
32. Dong, T.-Y.; Lin, S.-F.; Chen, C.-P.; Yeh, S.-W.; Chen, H.-Y.; Wen, Y.-S. Long-distance electronic interaction in a molecular wire consisting of ferrocenyl-ethynyl unit bridging two [(η5-C5H5)(dppe)M] metal centers Original Research Article. J. Organomet. Chem. 2009, 694, 1529.
33. Huang, P.-H.; Shen, J.-Y.; Wen, Y.-S. 3,4-Dinitro-2,5-bis[4-(trifluoromethyl)phenyl]thiophene. Acta  Cryst. E, 2009, 65, o1469.

Update： 2016-01-06

1. Huang, TH; Whang, WT; Shen, JY; Wen, YS; Lin, JT; Ke, TH; Chen, LY; Wu, CC Dibenzothiophene/oxide and quinoxaline/pyrazine derivatives serving as electron-transport materials. ADVANCED FUNCTIONAL MATERIALS 2006-07, 16(11), 1449-1456.
2. Dong, TY; Chang, SW; Lin, SF; Lin, MC; Wen, YS; Lee, L Toward the development of molecular wires: A terpyridine spacer containing polyferrocenylalkyne linkages. ORGANOMETALLICS 2006-04, 25(8), 2018-2024.
3. Huang, PH; Huang, TH; Shen, JY; Wen, YS 2,8-bis(diphenylamino)-5H-5 lambda(6)-dibenzo[b,d]thiophene 5,5-dioxide. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 2006-04, 62.
4. Huang PH, Shen JY, Huang TH, Wen YS, Lu KN N-(2 ',7 '-di-tert-butyl-9,9 '-spirobifluoren-2-yl) aniline. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 2006-04, 62.
5. Lu YL, Wu JY, Chan MC, Huang SM, Lin CS, Chiu TW, Liu YH, Wen YS, Ueng CH, Chin TM, Hung CH, Lu KL Influence of water content on the self-assembly of metal-organic frameworks based on pyridine-3,5-dicarboxylate. INORGANIC CHEMISTRY 2006-03, 45(6), 2430-2437.
6. Huang PH, Shen JY, Pu SC, Wen YS, Lin JT, Chou PT, Yeh MCP Synthesis and characterization of new fluorescent two-photon absorption chromophores. JOURNAL OF MATERIALS CHEMISTRY 2006-03, 16(9), 850-857.
7. Huang PH, Huang TH, Shen JY, Wen YS Pentacarbonyl[N,N-dimethyl-N '-( 5-{2-[5-(4-pyridyl-ethynyl) thiophen-2-yl]vinyl}thiophen-2-ylmethyl-ene) benzene-1,4-diamine]tungsten(0). ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 2006-03, 62.
8. Wu JY, Yeh TT, Wen YS, Twu J, Lu KL Unusual robust luminescent porous frameworks self-assembled from lanthanide ions and 2,2 '-bipyridine-4,4 '-dicarboxylate. CRYSTAL GROWTH & DESIGN 2006-02, 6(2), 467-473.
9. Wu HC, Thanasekaran P, Tsai CH, Wu JY, Huang SM, Wen YS, Lu KL Self-assembly, reorganization, and photophysical properties of silver(I)-Schiff-base molecular rectangle and polymeric array species. INORGANIC CHEMISTRY 2006-01, 45(1), 295-303.